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Glass Transition Temperature Tg Of Plastics

Thermoplastic resins melt when its temperature becomes higher than its melting point and becomes liquid, but as it is gradually cooled from the liquid state its viscosity gradually increases, and it goes into a rubbery state and it finally solidifies. The temperature at the border from the rubbery state to the solid state (called the glass state) is called its "glass transition temperature". The glass transition temperature is generally indicated as Tg.

Tg is a physical quantity that is determined by the type of plastic. By knowing the value of Tg, it is possible to estimate the time required for the molded item to cool inside the cavity and the molded item temperature at which it can be ejected from the mold.

The values of Tg are given below for the major plastics:

Name of plastic                                              Tg

Polyethylene                                                -125℃

Polypropylene                                                0℃

Polyvinyl chloride                                          87℃

Polystyrene                                                   100℃

ABS                                                               80-125℃

Polymethyl methacrylate                            90℃

Polyamide 6                                                   50℃

Polyamide 66                                                 50℃

Polyacetal                                                      -50℃

Polycarbonate                                               150℃

Polyphenylene sulfide                                 126℃

Polyurethane                                                 -20℃

Polyether sulfone                                         230℃

Polyphenylene oxide                                 104-120℃

Polyamide imide                                            275℃

Polylactic acid                                                 57℃

Polytetrafluoroethylene                               126℃

EVA                                                                   -42℃

Polyacrylonitrile                                            104℃

Polyfluoro vinylidene                                    35℃

Polypropylene terephthalate                       50℃

Polyethylene terephthalate                          69℃

 

 

 

Posted by Shine

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